N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide
نویسندگان
چکیده
منابع مشابه
N,N′-Dibenzyl-N,N′-dimethyl-N′′-(methylsulfonyl)phosphoric triamide
In the title compound, C(17)H(24)N(3)O(3)PS, the P and the S atoms are each in a distorted tetra-hedral environment and the N atoms display sp(2) character. The phosphoryl group and the NH unit are anti with respect to one another. The dihedral angle between the mean planes of the benzene rings is 31.08 (8)°. The crystal packing is stabilized by N-H⋯O hydrogen bonds, forming an extended chain p...
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The asymmetric unit of the title compound, C(23)H(28)N(3)OP, contains two independent mol-ecules with significant conformational differences. For example, the torsion angles N-C-C-C involving the N-benzyl moieties are 57.3 (7) and 11.6 (8)° in one mol-ecule and 76.5 (7) and 97.4 (7)° in the other. In each mol-ecule, the P atom exhibits a distorted tetra-hedral conformation [the bond angles at P...
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The P atom in the title mol-ecule, C(24)H(28)N(3)O(2)P, is in a distorted tetra-hedral P(=O)(N)(N)(2) environment. The phosphoryl group and the NH unit adopt a syn orientation with respect to each other and the N atoms have sp(2) character. The P-N bonds in the P(O)[N(CH(3))(CH(2)C(6)H(5))](2) unit are shorter than the P-N bond in the C(=O)NHP(=O) fragment. An intra-molecular C-H⋯O hydrogen bon...
متن کاملN,N′-Dibenzyl-N,N′-dimethyl-N′′-(4-nitrobenzoyl)phosphoric triamide
The P atom in the title compound, C(23)H(25)N(4)O(4)P, is in a slightly distorted tetra-hedral coordination environment and the N atoms show sp(2) character. The phosphoryl group and the NH unit are syn with respect to each other. In the crystal, pairs of inter-molecular N-H⋯O(P) hydrogen bonds form centrosymmetric dimers.
متن کاملN,N′-Dibenzyl-N′′-(4-bromobenzoyl)-N,N′-dimethylphosphoric triamide
In the title compound, C(23)H(25)BrN(3)O(2)P, the P atom has a distorted tetra-hedral coordination. In the crystal structure, the mol-ecules form centrosymmetric dimers via pairs of essentially linear N-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811015832